Essential oils are complex substances. Their medicinal properties originate from components such as monoterpenes and sesquiterpenes. These are compounds consisting of 10 (mono) or 15 (sesqui) carbon atoms, which can also have an oxygen atom attached in the form of alcohol, aldehyde, acid, or ketone. They also contain a few weak carbon double bonds characteristic of unsaturated fatty acids. When monoterpenoids and sesquiterpenoids are exposed to air, they undergo an oxidation process: alcohol is transformed into aldehyde, and aldehyde can transform into acid. Sounds familiar? This is the same process responsible for spoiling wine and turning it into vinegar when accidentally exposed to air during storage.
Some monoterpenoids, such as geraniol (found in essential oils like geranium Pelargonium graveolens and grapefruit Citrus Paradisi), are more prone to oxidation. Others, like linalool (found in essential oils like lavender), are more stable. Additionally, the carbon double bonds can also become single and trap oxygen atoms, forming oxides, epoxides, and peroxides.
The Smell of Rancid Vegetable Oil
Have you ever had vegetable oil turn rancid in your pantry? That particular smell reveals the same chemical process. Almost all constituents of essential oils are unsaturated compounds containing carbon, so they can undergo the same reaction, spoiling or oxidizing. Although unpleasant odors are not perceived in essential oils, they should be avoided if they have undergone oxidation.